In the meantime, the chemical factories of Continental Europe, principally in Germany, Austria and Belgium, had taken hold of the novelty and under the collective name of lithopone or lithophone, by numerous processes, produced various grades of the pigment, branding the respective qualities as red seal, green seal, yellow seal, blue seal, etc., or selling them under some fancy name. Of this we shall speak later on. The crusade against the use of white lead in the various countries of Continental Europe, assisted the manufacturers, to a very great extent, in marketing their products, not only to industrial concerns, as has been the case in this country, until recently, but to the general painting trade. Up to 1889 the imports into this country were comparatively small. At that time one of the largest concerns manufacturing oilcloth and linoleum in the State of New Jersey began to import and use Charlton white. Shortly after that other oilcloth manufacturers followed suit, replacing zinc white with lithopone in the making of white tablecloth, etc., and later on abandoning the use of white lead in floor cloth and linoleum. This gave an impetus to several chemical concerns, that erected plants and began to manufacture the pigment. Competition among the manufacturers and the activity of the importers induced other industries to experiment with lithopone, and the shade cloth makers, who formerly used white lead chiefly, are now among the largest consumers. Makers of India rubber goods, implement makers and paint manufacturers are also consumers of great quantities, and the demand is very much on the increase, as the nature of the pigment is becoming better understood and its defects brought under control. Large quantities find their way into floor paints, machinery paints, implement paints and enamel paints, while the flat wall paints that have of late come into such extensive use owe their existence to the use of lithopone in their makeup.
Notes on contributors
The trouble with titanium dioxide, by Siloam Springs Regional Hospital, Herald Leader, October 4, 2023
Prices increased somewhat in the Asian market during the third quarter of 2021. After a steady recovery since mid-June, its price in India fell slightly in August, pushed down by lower import prices. Titanium dioxide prices continued to rise in the Chinese domestic market, with FOB Wuhu talks for Rutile grade TiO2 settling at 3125 USD/MT for the week ending September 24th.
So if you’re worried about titanium dioxide, don’t be! With current research and industry recommendations, titanium dioxide is a safe food additive. And if you want to avoid it, that’s ok too! Just don’t expect certain foods to be so white, smooth, and bright.
Color, compared with standard samples
Titanium is one of the most common metals on earth, but it does not occur naturally in this elemental form. TiO2, also known as titanium (IV) oxide or titania, is the naturally occurring compound created when titanium reacts with the oxygen in the air. As an oxide, titanium is found in minerals in the earth’s crust. It is also found with other elements, including calcium and iron.
When it comes to painting, there are many factors to consider. From choosing the right color to ensuring the durability and longevity of your paint, every decision counts. A key ingredient that plays a vital role in achieving the desired finish is titanium dioxide. This extraordinary white pigment revolutionized the paint industry, giving walls around the world unparalleled luster and durability.
The successful completion of 2022. Looking at the development of Titanium Dioxide market in this year, from the perspective of price, according to the monitoring of bulk commodity data, the price of titanium dioxide will fall in 2022. The average price of domestic titanium dioxide at the beginning of the year was 20733.33 yuan/ton, and the average price at the end of the year was 15933.33 yuan/ton. The price fell by 23.15% during the year.
2. Market analysis
Product quotation
From the perspective of market development in 2022, prices in the first half of the year are basically in a stable stage, with little fluctuation, and prices in the second half of the year are in a rapid decline stage. In November, Longqi sent a letter to raise the price to stabilize the price. At this time, the price of titanium dioxide began to stabilize and stop falling.
In the first quarter, export orders performed well, and the market confidence of titanium dioxide enterprises was good. Before the year, domestic downstream manufacturers mainly hoarded goods moderately before the year. The market rose twice, with a cumulative increase of 1.77% from January to March. The ex factory quotation of domestic rutile titanium dioxide including tax is mostly 20000-22000 yuan/ton; The ex factory quotation of anatase titanium dioxide including tax is between 18000-19500 yuan/ton. After the year, the domestic raw material sulfuric ACID price continued to rise, the enterprise cost was under pressure, and the support was strong. The titanium dioxide market confidence was fair, and the price continued to rise.
In the second quarter, the logistics management and control and the domestic market turnover were light. Affected by logistics control and other factors, transportation is relatively difficult, market supply is shrinking, traders are unstable, and the market price declines with the focus on digesting their own inventory. The cumulative decline from April to June was 3.08%. The ex factory quotation of domestic rutile titanium dioxide including tax is between 19100-22000 yuan/ton; The ex factory quotation of anatase titanium dioxide including tax is between 17800-19000 yuan/ton. The spot market of titanium ore continued to decline, the price of sulfuric acid also continued to decline, and the cost support was weak. At the same time, the performance of the downstream terminal real estate market is poor. Under the superposition of multiple negative factors, the titanium dioxide market fell.
In the third quarter, Longqi guided the price reduction and the titanium dioxide market fell sharply. 7-9 The cumulative decline was 19.85%. The ex factory quotation of domestic rutile titanium dioxide including tax is mostly between 15500-17000 yuan/ton; The quotation of anatase titanium dioxide is between 14500-15500 yuan/ton. Due to the limited power supply and other factors, the titanium dioxide enterprises in southwest China have reduced their production. The market price of raw sulfuric acid fell rapidly, and the cost support was weak. In addition, the domestic titanium dioxide market demand continues to be sluggish, and the manufacturer's inventory pressure is still large.
In the fourth quarter, Dragon Enterprise sent a letter in November to promote stability. The cumulative decline was 2.55% from October 12. The titanium dioxide market is about to enter the off-season, and the demand market for coatings is tepid, especially in the northern market. In November, the group announced that the price would rise, and the prices offered by various manufacturers were flexible, so it was more meaningful to stop the decline. Most domestic rutile titanium dioxide prices are between 15000-17500 yuan/ton; The quotation of anatase titanium dioxide is about 14000-14500 yuan/ton. The price of titanium concentrate in Panxi increased. More than 20 domestic titanium dioxide enterprises sent letters to announce the increase, and the international giants Chemurs and Tronox announced the reduction of titanium dioxide production in the fourth quarter, which also benefited the domestic titanium dioxide market and stabilized the market on the whole.
Why all of a sudden is there so much interest in the safety of Titanium Dioxide?
Researchers from France and Luxembourg gave E171 (the much more food friendly name for Titanium Dioxide) in Europe and the United States, to lab rats in their drinking water for 100 days.
Of those rats, 40 per cent of the exposed rodents developed “preneoplastic lesions” or precancerous growths. The Titanium Dioxide also inhibited the immune systems of the rats and “accelerated” the growth of the lesions. France’s INRA agricultural research institute, which took part in the study, said in a statement.“These results demonstrate a role in initiating and promoting the early stages of colorectal cancer formation,” though it said no conclusion could be drawn about later phases of cancer, or of any danger to humans……….(not till they test it on us!!)
The results of the study were published in the Nature journal Scientific Reports.